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Intermolecular Stetter reaction of aromatic aldehydes with(E)-(2-nitrovinyl)cyclohexane induced by N-heterocyclic carbene and thiourea 被引量:1

Intermolecular Stetter reaction of aromatic aldehydes with(E)-(2-nitrovinyl)cyclohexane induced by N-heterocyclic carbene and thiourea
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摘要 Intermolecular Stetter reaction of aromatic aldehydes with(E)-(2-nitrovinyl)cyclohexane catalyzed by thiazolium A has been developed.The reaction rate and efficiency are profoundly impacted by the presence of thiourea B.The reaction affords moderate to good yields of the Stetter product.Some factors influencing yield were discussed. Intermolecular Stetter reaction of aromatic aldehydes with(E)-(2-nitrovinyl)cyclohexane catalyzed by thiazolium A has been developed.The reaction rate and efficiency are profoundly impacted by the presence of thiourea B.The reaction affords moderate to good yields of the Stetter product.Some factors influencing yield were discussed.
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 2016年第7期1032-1035,共4页 中国化学快报(英文版)
基金 supported by the Prospective Research Funds of Jiangsu Provincial Department of Science and Technology (No. BY2015049-02) the Open-end Funds of Jiangsu Key Laboratory of Marine Biotechnology, Huaihai Institute of Technology, (No. 2014HS005) the Funds of Technology Research of Lianyungang (No. CG1301)
关键词 Intermolecular Stetter reaction N-heterocyclic carbene THIOUREA Thiazolium NITROALKENE β-Nitro ketone Intermolecular Stetter reaction N-heterocyclic carbene Thiourea Thiazolium Nitroalkene β-Nitro ketone
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