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Preparation of PtSn_2–SnO_2/C nanocatalyst and its high performance for methanol electro-oxidation

Preparation of PtSn_2–SnO_2/C nanocatalyst and its high performance for methanol electro-oxidation
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摘要 PtSn2-SnO2/C nanocatalyst was prepared by co-reduction of Pt and Sn precursor at ca,15℃.The formation of PtSn2-SnO2 nanoparticle was determined by XRD,TEM and XPS characterization.This PtSn2-SnO2/C nanocatalyst exhibits stronger resistance to CO poisoning and effectively improves methanol electro-catalytic effect,up to 3 times than the commercial Pt/C catalyst. PtSn2-SnO2/C nanocatalyst was prepared by co-reduction of Pt and Sn precursor at ca,15℃.The formation of PtSn2-SnO2 nanoparticle was determined by XRD,TEM and XPS characterization.This PtSn2-SnO2/C nanocatalyst exhibits stronger resistance to CO poisoning and effectively improves methanol electro-catalytic effect,up to 3 times than the commercial Pt/C catalyst.
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 2016年第7期1083-1086,共4页 中国化学快报(英文版)
基金 supported by NSFC (Nos. 21373116 and 21421001) the Tianjin Natural Science Research Fund (No. 13JCYBJC18300) RFDP (No. 20120031110005) the MOE Innovation Team (No. IRT13022) of China
关键词 Direct methanol fuel cell PtSn2–SnO2/C nanocatalyst Methanol electro-oxidation Low temperature preparation CATALYSIS Electrochemical impedance Direct methanol fuel cell PtSn2–SnO2/C nanocatalyst Methanol electro-oxidation Low temperature preparation Catalysis Electrochemical impedance
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