摘要
综述了基于C—N键断裂的芳基肼参与的偶联反应,主要包含自由基偶联反应以及过渡金属催化自身偶联反应、Suzuki反应和Heck反应等方面的研究进展.这些研究表明芳基肼是一个非常高效的芳基来源.
As a special synthons containing C--N bond, hydrazine chemistry has attracted a growing interest of chemists due to its versatility in cross-coupling arylation. This review summarizes the recent advances in the coupling reactions of arylhy- drazine, which is utilized as an effective arylation reagent in radical reactions, and transition metal-catalyzed homocoupling, Suzuki coupling and Heck coupling via C--N bond cleavage.
出处
《有机化学》
SCIE
CAS
CSCD
北大核心
2016年第8期1790-1796,共7页
Chinese Journal of Organic Chemistry
基金
国家自然科学基金基金(Nos.21502075,21502069,201502069)
浙江省自然科学基金(No.LQ15B020006)
浙江省教育厅一般科研(No.Y201431173)资助项目~~
关键词
C—N键断裂
芳基肼
偶联反应
自由基
C--N bond cleavage
aryl hydrazine
coupling reaction
radical
