摘要
由于Bi_2VO_(5.5)材料作为电解质在低较温度下具有较高的氧离子电导率,是用作中低温制氧机理想的电解质材料。优选出双掺杂的Bi_2V_(0.9)Cu_(0.075)Nb_(0.025)O_(11-δ)电解质陶瓷膜具有最高的氧离子电导率,并提高了机械性能;用共沉淀法合成的电解质粉体,可改善电解质陶瓷膜的性能;La_(0.6)Sr_(0.4)Co_(0.8)Fe_(0.2)O_3和Bi_2Cu_(0.1)V_(0.9)O_(5.35)混合氧化物是BIMEVOX电解质陶瓷膜最优的电极材料。对双掺杂金属离子、合成方法和电极材料对BIMEVOX电解质陶瓷膜性能影响进行了介绍。
The Bi_2VO_（5.5） is a kind of ideal electrolyte materials in oxygen generator at the middle low temperature because it has high oxygen ion conductivity at low temperature. The double doped Bi_2V_（0.9）Cu_（0.075）Nb_（0.025）O_（11-δ） electrolyte ceramic membrane with the highest oxygen ion conductivity is optimized, and the mechanical properties are improved. The electrolyte powders synthesized by co-precipitated method can improve the properties of the electrolyte membrane. The mixed oxides of La_（0.6）Sr_（0.4）Co_（0.8）Fe_（0.2）O_3 and Bi_2Cu_（0.1）V_（0.9）O_（5.35） is optimal electrode materials of BIMEVOX electrolyte ceramic membrane. In this paper, the effect of double-doped metal ion, synthesis method and electrode material on the properties of BIMEVOX electrolyte ceramic membrane is reviewed.
作者
王彩英
李慧琴
郝先库
张瑞祥
刘海旺
王士智
WANG Caiylng LI Huiqin HAO Xianku ZHANG Ruixiang LIU Haiwang WANG Shizhi(Baotou Light Industry Vocational and Technology College, Baotou 014035, China School of Materials and Metallurgy, Inner Mongolia University of Science Technology, Baotou 014010, China Baotou Research Institute of Rare Earths, Baotou 014030. China)
出处
《中国陶瓷》
CAS
CSCD
北大核心
2016年第9期1-7,共7页
China Ceramics
关键词
BIMEVOX
电解质陶瓷膜
合成方法
双掺杂
电极材料
BIMEVOX
Electrolyte ceramic membrane
Double doped metal ions
Synthesis method
Electrode material
