摘要
Pressure effect on the electrical conductivity of San Carlos olivine was investigated by the newly installed electrical conductivity measurement system at China University of Geosciences. Electrical conductivity of San Carlos olivine aggregates was measured up to 12 GPa and 1475 K using the Walker-type multi-anvil apparatus equipped with eight WC cubes as the second-stage anvils. The pressure generation against applied load for the experimental assemblage was examined by phase transition of Bi, quartz, forsterite under different P-T conditions. To check the data validity of this new system, electrical conductivities of the serpentinites and talc samples were measured. The results are consistent with the published data of the same samples. Electrical conductivity （σ） of the San Carlos olivine aggregates and temperature （T） satisfy the Arrhenian formula： σ=σ0exp[-（△E＋P△V）/kT]. The pre-exponential factor （σ0）, activation energy （AE） and activation volume （AV） yield value of 7.74 S/m, 0.85 eV and 0.94 cm^3/mol, respectively. Electrical conductivities of the San Carlos olivine aggregates decline with increasing pressure at same temperatures. The negative pressure effect can be interpreted by strain energy model of defect energy together with the lattice deformation. In addition, the electrical conductivity-depth 1-D profile of the upper mantle was constructed based on our results and some assumptions. The calculated profile is concordant with the geophysical observation at the depth of 180-350 km beneath Europe, which indicates that the upper mantle beneath Europe might be dry.
Pressure effect on the electrical conductivity of San Carlos olivine was investigated by the newly installed electrical conductivity measurement system at China University of Geosciences. Electrical conductivity of San Carlos olivine aggregates was measured up to 12 GPa and 1475 K using the Walker-type multi-anvil apparatus equipped with eight WC cubes as the second-stage anvils. The pressure generation against applied load for the experimental assemblage was examined by phase transition of Bi,quartz, forsterite under different P-T conditions. To check the data validity of this new system, electrical conductivities of the serpentinites and talc samples were measured. The results are consistent with the published data of the same samples. Electrical conductivity(σ) of the San Carlos olivine aggregates and temperature(T) satisfy the Arrhenian formula: σ=σ0exp[.(ΔE+PΔV)/kT].The pre-exponential factor(σ0), activation energy(ΔE) and activation volume(ΔV) yield value of 7.74 S/m, 0.85 eV and 0.94cm3/mol, respectively. Electrical conductivities of the San Carlos olivine aggregates decline with increasing pressure at same temperatures. The negative pressure effect can be interpreted by strain energy model of defect energy together with the lattice deformation. In addition, the electrical conductivity-depth 1-D profile of the upper mantle was constructed based on our results and some assumptions. The calculated profile is concordant with the geophysical observation at the depth of 180–350 km beneath Europe, which indicates that the upper mantle beneath Europe might be dry.
基金
supported by the National Natural Science Foundation of China (Grant No. 41472040)
the Fundamental Research Funds for the Central Universities (Grant Nos. G1323531510, CUGL150801)
the MOST Special Fund from the State Key Laboratory of Geological Processes and Mineral Resources, China University of Geosciences (Grant No. MSFGPMR201408)
