Highly linear polyethylenes using the2-(1-(2,4-dibenzhydrylnaphthylimino)ethyl)-6-(1-(arylimino)ethyl)-pyridylcobalt chlorides: synthesis, characterization and ethylene polymerization

The series of 2-（1-（2,4-dibenzhydrylnaphthylimino）ethyl）-6-（1-（arylimino）ethyl）pyridine derivatives and their cobalt chlorides （Col-Co5） were synthesized and fully characterized. The representative complexes Co2 and Co3 were confirmed by single crystal X-ray diffraction analyses, indicating pseudo-square-pyramidal geometry around the cobalt centre. All cobalt complexes, activated with either methylaluminoxane （MAO） or modified methylaluminoxane （MMAO）, exhibited high activities towards ethylene polymerization, and produced polyethylenes with high molecular weight and highly linear feature as well as unimodal distribution.

The series of 2-(1-(2,4-dibenzhydrylnaphthylimino)ethyl)-6-(1-(arylimino)ethyl)pyridine derivatives and their cobalt chlorides(Co1.Co5) were synthesized and fully characterized. The representative complexes Co2 and Co3 were confirmed by single crystal X-ray diffraction analyses, indicating pseudo-square-pyramidal geometry around the cobalt centre. All cobalt complexes,activated with either methylaluminoxane(MAO) or modified methylaluminoxane(MMAO), exhibited high activities towards ethylene polymerization, and produced polyethylenes with high molecular weight and highly linear feature as well as unimodal distribution.