含硫碳硼烷配位的后过渡金属有机化合物及其合成

Synthesis of Late Transition Metal Complexes Based on Chalcogenola to Carborane Ligands

有机金属含硫族化学是现代无机化学和配位化学研究中的重要研究领域之一,它充分展示了硫族元素和金属中心配位的多样性.综述了各类含硫碳硼烷配体的制备及其与后过渡金属化合物(主要包括第九、十和十一族金属)之间的反应性,且对相应的金属有机化合物在金属—金属成键、小分子活化和生物医学等方面的应用作了简要介绍.

Organometallic chalcogenolate chemistry, which represents the coordination diversity between chalcogenide and metal center, is one of the important research fields in modern inorganic and coordination chemistry. The preparation of chalcogenolate carborane ligands and their reactivity with late transition metal compounds （including group 9, 10 and 11 metal） were summarized, and the diverse application of the obtained corresponding organometallic complexes in many areas, such as metal--metal bond formation, small molecular activation and bio-medicine was briefly introduced.