摘要
有机金属含硫族化学是现代无机化学和配位化学研究中的重要研究领域之一,它充分展示了硫族元素和金属中心配位的多样性.综述了各类含硫碳硼烷配体的制备及其与后过渡金属化合物(主要包括第九、十和十一族金属)之间的反应性,且对相应的金属有机化合物在金属—金属成键、小分子活化和生物医学等方面的应用作了简要介绍.
Organometallic chalcogenolate chemistry, which represents the coordination diversity between chalcogenide and metal center, is one of the important research fields in modern inorganic and coordination chemistry. The preparation of chalcogenolate carborane ligands and their reactivity with late transition metal compounds (including group 9, 10 and 11 metal) were summarized, and the diverse application of the obtained corresponding organometallic complexes in many areas, such as metal--metal bond formation, small molecular activation and bio-medicine was briefly introduced.
出处
《上海应用技术学院学报(自然科学版)》
2016年第3期213-217,285,共6页
Journal of Shanghai Institute of Technology: Natural Science
基金
国家自然科学基金资助项目(21174081
21102088)
上海应用技术学院引进人才基金资助项目(YJ2015-29
YJ2016-10)
关键词
碳硼烷
配位
后过渡金属
合成
反应性
carborane
coordination
late transition metal
synthesis
reactivity