醇烃混合裂解热力学分析

THERMODYNAMIC ANALYSIS FOR ALCOHOL HYDROCARBON MIXED PYROLYSIS

以甲醇和正十二烷混合裂解作为模型反应,进行了热力学计算。考察了不同耦合组成在不同温度条件下反应的热效应。计算结果表明,甲醇同正十二烷耦合行为受温度和组成的影响,醇烃混合裂解热力学分析研究为后续的实验工作打下了理论基础。

Thermodynamic calculation is done with mixed pyrolysis of methanol and n - Dodecane as model reaction. It is checked the heat effects of reaction with different coupling component under different tempera- ture. It is showed from the calculation that the coupling action of methanol ＇and n - Dodecane is affected by temperature and the component. This research plays a theoretic base for the following experiment.