摘要
光降解是许多药物类污染物在地表水中的重要去除方式。在UV-vis照射下,研究水体中的无机离子对布洛芬光降解的影响。结果表明,在反应液中添加金属离子和碳酸氢根时,布洛芬的光降解都很好的符合准一级动力学。金属阳离子和HCO-3均可抑制布洛芬的光降解,且抑制率随添加浓度的增大而增大。
Photodegradation is likely to be an important loss mechanism for many pharmaceutical pollutants in surface water. The effects of inorganic ions on ibuprofen( IBP) photolysis in aqueous media are studied under UV- vis irradiation. The results show that the degradation of ibuprofen complies with the pseudo- first- order kinetics model when metal cations or bicarbonate is added individually into the solution. Metal cations and bicarbonateall can inhibit the photodegradation of ibuprofen,and the inhibition rate increases with the increase of concentration.
作者
李富华
陈敏
孔青青
张铭辉
刘国光
吕文英
姚琨
LI Fuhua CHEN Min KONG Qingqing ZHANG Minghui LIU Guoguang LYU Wenying YAO Kun(School of Environmental Science and Engineering, Guangdong University of Technology Guangzhou 510006)
出处
《工业安全与环保》
北大核心
2016年第10期8-10,共3页
Industrial Safety and Environmental Protection
基金
国家自然科学基金(21377031)
关键词
布洛芬
无机离子
光降解
动力学
ibuprofen
inorganic ions
photodegradation
kinetics