典型南方水源氨基酸浓度变化与去除

Concentration Variation and Removal of Amino Acids in Typical Drinking Sources in the South of China

氨基酸是天然水体中含氮有机物的重要组成部分,为明晰氨基酸在水库原水中的浓度变化及去除情况,于2015年5-10月利用高效液相色谱法（HPLC）对我国南方某市3个主要水库原水中20种常见氨基酸浓度进行连续监测,分析该市水库原水中氨基酸的空间分布与变化趋势,同时研究了不同处理工艺对氨基酸的去除情况.结果表明,不同水库原水中氨基酸组成有所差异,但主要氨基酸为天冬氨酸、半胱氨酸、亮氨酸.水库C原水中各氨基酸含量没有明显季节性变化趋势,但夏季含量相对较低,秋季相对较高.此外,常规工艺与BAC-UF工艺对氨基酸的主要去除单元为混凝沉淀单元,O3-BAC工艺对氨基酸的主要去除单元为主臭氧.常规工艺、BAC-UF工艺、O3-BAC工艺对氨基酸总量的总去除率分别为94.42%、66.04%、49.75%.

Amino acids are the main components of nitrogenous organic matter in surface water. In order to reveal the concentration variation and removal of amino acids in reservoirs water,the concentration variation of the twenty common amino acids for three main reservoirs＇ water in a typical southern city of China was monitored between May and October in the year of 2015 by HPLC,and the space distribution and change trend of the twenty amino acids were analyzed. In addition,the removal of the twenty amino acids was also studied by different water treatment processes. The results showed that the amino acids contents and composition were different among the three reservoirs. Aspartic acid,cysteine and leucine were the main amino acids for the three reservoirs. Besides,there was no obvious seasonal variation of amino acids content for reservoir C. However,the concentration of amino acids in autumn was higher than that in summer. Coagulation and sedimentation were main units for the removal of amino acids in conventional and BAC-UF processes while O3 oxidation was the main unit in O3-BAC process. 94. 42%,66. 04% and 49. 75% of total amino acids contents were removed by the conventional,BAC-UF and O3-BAC processes,respectively.