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降冰片烯酰亚胺型双苯并嗪的合成及性能 被引量:3

Preparation and properties of norbornene-imide-functionalized bis-benzoxazine
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摘要 首先用降冰片烯二酸酐、对氨基苯酚为原料合成降冰片烯酰亚胺(NI),然后用合成的NI、4,4-二氨基二苯醚(ODA)和多聚甲醛为原料进行Mannich反应合成出降冰片烯酰亚胺型双苯并嗪(NI-BOZ),经高温固化后形成热固性树脂。用FTIR、1H NMR、13C NMR分析了NI和NI-BOZ的化学结构,证实了所得的目标产物;用DSC对NI-BOZ的固化动力学进行研究;用DMA和TGA分析了NI-BOZ的固化物的热性能。结果表明:NI-BOZ的固化反应活化能为86.27 k J·mol-1,反应级数为0.91;poly(NI-BOZ)树脂空气条件下的玻璃化转变温度为215℃,氮气条件下失重5%的温度为445℃,失重10%的温度为467℃,在800℃的残碳率为63%。 Norbornene imide(NI), which was prepared from carbic anhydride and p-aminophenol, together with 4,4-2 amino diphenyl ether(ODA) and paraformaldehyde, was used to synthesize norbornene-imidefunctionalized benzoxazine(NI-BOZ) via Mannich reaction. A novel thermosetting resin was obtained from high temperature curing of NI-BOZ. Structure of NI and NI-BOZ were characterized by FTIR, 1H NMR and 13 C NMR. Curing kinetics of NI-BOZ was monitored by DSC and thermal properties of poly(NI-BOZ) were evaluated by DMA and TGA. The results showed that the activation energy of NI-BOZ thermal curing was 86.27 k J·mol-1 and the reaction order was 0.91. Poly(NI-BOZ) had glass transition temperature(Tg) of 215℃ in air environment. The polymer had 5% mass loss at 445℃, 10% mass loss at 467℃ and 63% char yield at 800℃ under nitrogen.
出处 《化工学报》 EI CAS CSCD 北大核心 2016年第11期4899-4905,共7页 CIESC Journal
基金 国家自然科学基金项目(51273054)~~
关键词 降冰片烯酰亚胺 苯并嗪 合成 核磁共振 热性能 热固性树脂 norbornene-imide benzoxazine synthesis NMR thermal performance thermosetting resin
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  • 1景晓辉.聚酰胺酸合成工艺与聚酰亚胺膜制备及表征[J].应用化工,2004,33(6):33-36. 被引量:8
  • 2Hergenrother P M. The use, design, synthesis, and proper- ties of high performance/high temperature polymers:an overview[ J]. High Performance Polymers ,2003,15 ( 1 ) : 3--45.
  • 3Lee M, Khan S B, Akhtar K, et al. Fuel cell : synthesis and properties of polyimide for PEMFC at high temperature [ J]. Int J Electrochem Sci,2013,8:4225-4233.
  • 4Sroog C E. Polyimides [ J ]. Progress in Polymer Science (UK) ,1991,16(4) :561-694.
  • 5Cella J A. Degradation and stability of polyimides [ J ]. Polymer Degradation and Stability, 1992,36 (2) :99-110.
  • 6Meador M A B, Johnston J C, Cavano P J. Elucidation of the cross-link structure of nadie-end-capped polyimides using NMR of 13C-labeled polymers [ J ]. Macromole- eules, 1997,30(3) :515-519.
  • 7Selladurai M, Sundararajan P R, Sarojadevi M. Synthesis, thermal and mechanical properties of modified PMR/car- bon fiber composites [ J ]. Chemical Engineering Journal, 2012,203:333-347.
  • 8Wilson D. PMR-15 processing,properties and problems -- a review[ J ]. British Polymer Journal, 1988,20 (5):405- 416.
  • 9Meador M A B, Johnston J C, Frimer A A, et al. On the oxidative degradation of nadic end-capped polyimides. 3. Synthesis and characterization of model compounds for end-cap degradation products [ J ]. Macromolecules, 1999, 32(17) :5532-5538.
  • 10Renner A, Kramer A. Allylnadic-imides: A new class of heat-resistant thermosets [ J ]. Journal of Polymer Science Part A: Polymer Chemistry, 1989,27 (4) : 1301-1323.

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