摘要
采用溶胶-凝胶法在LaNiO_3/Si(100)底电极上成功制备了Zr/Ti摩尔比不同的Pb_(0.88)La_(0.08)(Zr)xTi_(1-x))O_3(x=0.30,0.55,0.80)的厚膜,研究了Zr/Ti摩尔比对PLZT反铁电厚膜的结构与储能行为的影响。结果表明:Zr/Ti摩尔比对PLZT反铁电厚膜的结构无太大影响;随着锆钛比中锆含量的增加,储能密度和储能效率呈现逐渐增加的趋势,其中PLZT(8/80/20)厚膜在电场强度为1400kV/cm时储能密度达到最大,为23.8J/cm^3,储能效率高达60.0%。
The different different zirconium content in Pb0.88La0.08(ZrxTi1-x)O3(x=0.30,055,0.80)(abbreviated as PLZT) thick films with 1μm thickness were successfully fabricated on LaNiO3/Si(100) by the sol-gel method. The effect of different zirconium content of the PLZT anti-ferroelectric thick films on the dielectric and energy-storage properties were studied scientifically. The results show that the structure of the PLZT anti-ferroelectric thick films was not affected, after zirconium content performance enhanced significantly, when ratio is (8/80/20), the energy-storage density (W) and energy-storage efficiency (η) were increased, and the maximum W=23.8J/cm^3 and corresponding η=60% were obtained from the PLZT(8/80/20) thick films at 1400 kV/cm.
出处
《稀有金属材料与工程》
SCIE
EI
CAS
CSCD
北大核心
2016年第10期2653-2658,共6页
Rare Metal Materials and Engineering
基金
国家自然科学基金(51462027)
'973'计划前期研究专项(2014CB660811)