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纳米氧化锌-粘胶复合纤维的制备及其阻燃性能表征

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摘要 本文中利用纳米级氧化锌作为阻燃剂,通过湿法纺丝工艺制备出纤维素/纳米ZnO纤维。通过扫描电镜、热重分析仪、极限氧指数仪、锥形量热仪等测试分析方法,对粘胶纤维、纤维素/ZnO纤维材料的热性能、燃烧性能等进行了系统的研究分析。通过热重分析仪(TG)对纤维的热降解过程进行了研究,结果表明,添加了纳米氧化锌的复合粘胶纤维的热分解残余量增加,都能催化纤维素脱水炭化。纤维素/ZnO纤维热分解温度明显提前,而且生成的碳质残渣稳定性好。通过扫描电镜(SEM)观察得知,纤维素/ZnO纤维灼烧后炭化膨胀,形成较稳定的膨胀炭层。通过极限氧指数仪(LOI)和锥形量热仪(CONE)对纤维的燃烧性能进行了研究,结果表明,ZnO对粘胶纤维的氧指数提高明显,加人了过渡金属氧化物ZnO的纤维燃烧危险性降低,ZnO抑烟效果显著。另一方面,添加的过渡金属氧化物ZnO也使纤维的CO生成量增加,烟气毒性有所提高。
出处 《中国阻燃》 2016年第6期2-7,共6页
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参考文献10

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