手性配位聚合物的构筑及其应用

Construction and Application of Chiral Coordination Polymers

手性配位聚合物因其结构多样性、可调控性以及潜在的多功能性,已经成为当前化学和材料学的研究热点。在合成中,可以通过选择特定的非手性配体、手性配体、手性溶剂或手性模板剂等来构筑手性配位聚合物。此外,还可以选择特定的金属离子赋予目标手性配位聚合物光、电、磁、催化和非线性光学等性能。本文详细综述了近年来纯手性配位聚合物的合成方法,以及在手性分离、手性催化、非线性光学、铁电和多铁等领域的应用研究进展。最后,对手性配位聚合物的合成方法及应用前景进行了展望。

Chiral coordination polymers （CPs） have become present one of research hot points in chemistry and materials science due to their structural diversities and adjustability, and potential muhifunctional properties. In the synthesis process, we generally choose achiral ligands, chiral ligands, chiral solvents and chiral templates in order to obtain chiral CPs. In addition, by selecting the specific metallic cations, we can embed the as-prepared chiral CPs with the fluorescent, electric, magnetic, catalytic and nonlinear optical properties. In this work, the research progresses in synthesis methods and applications of chiral CPs in chiral separation, chiral catalysis, nonlinear optics, ferroelectric and multiferroic properties are discussed in details. Finally, the synthesis methods and applications of chiral CPs are prospected.