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二氧化氯氧化降解含氨基硫脲废水研究 被引量:3

Study on degradation of wastewater containing thiosemicarbazide by ClO_2
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摘要 Oxidation degradation of wastewater containing thiosemicarbazide by ClO 2 has been studied.The results indicate that thiosemicarbazide is degradated to the nontoxic inorganics,including SO 2- 4,N 2 and CNO -.It has been proved that the mass ratio of ClO 2 to thiosemicarbazide and pH influence the removal ratio of COD obviously,but reaction time and temperature have weak effect.When pH≤2,R=2.0 and reaction time is 15min,removal ratio of COD achieves the highest value at ordinary temperature.Removal ratio of COD of pesticide wastewater containing thiosemicarbazio is about 86.0% under such condition indicating that the degradation effect is good. Oxidation degradation of wastewater containing thiosemicarbazide by ClO 2 has been studied.The results indicate that thiosemicarbazide is degradated to the nontoxic inorganics,including SO 2- 4,N 2 and CNO -.It has been proved that the mass ratio of ClO 2 to thiosemicarbazide and pH influence the removal ratio of COD obviously,but reaction time and temperature have weak effect.When pH≤2,R=2.0 and reaction time is 15min,removal ratio of COD achieves the highest value at ordinary temperature.Removal ratio of COD of pesticide wastewater containing thiosemicarbazio is about 86.0% under such condition indicating that the degradation effect is good.
出处 《化学研究与应用》 CAS CSCD 北大核心 2002年第4期490-492,共3页 Chemical Research and Application
关键词 二氧化氯 氧化降解 氨基硫脲 农药废水 废水处理 chlorine dioxide thiosemicarbazide degradation pesticide wastewater
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