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果糖衍生手性酮催化剂的合成

Synthesis of A Chiral Ketone Catalyst Derived from D-fructose
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摘要 以D-果糖为原料,经缩酮化、氧化、选择性水解和酯化等反应合成了果糖衍生手性酮催化剂,总收率68%,其结构经1H NMR确证。 A D-fructose derived chiral ketone catalyst with overall yield of 68% was synthesized by the reaction of ketal, oxidation, deketalization and acetylation, using D-fructose as starting material. The structure was confirmed by 1H NMR.
作者 张昊 周燕 陈瑶 薛志勇
机构地区 武汉纺织大学化学与化工学院
出处 《合成化学》 CAS CSCD 2016年第11期976-978,986,共4页 Chinese Journal of Synthetic Chemistry
基金 国家自然科学基金资助项目(21602163) 湖北省教育厅中青年人才项目(Q20161607) 湖北省自然科学基金资助项目(2016CFB261)
关键词 D-果糖 手性酮催化剂 一锅法合成 D-fructose chiral ketone catalyst one-pot synthesis
分类号 O625.15 [理学—有机化学]
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参考文献17

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合成化学
2016年 第11期

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