摘要
[ Objective] In order to provide a reference for safe and reasonable use of pyrethroids in cigarette production, the degradation behaviors of three kinds of pyrethroids in cigarette production environment were studied. [ Method ] Three kinds of pyrethroids （permethrin, cyfluthrin and c/s-cypermethrin） were adminis- trated to two media （cut tobacco and iron sheet surface） in cigarette production environment at MRLs concentration, and the first sampling was conducted at 24 d post administration. Afterwards, sampling was performed once every 7 d, with a total of six times. The degradation rates of insecticides in different media were cal- culated, and degradation models were established. [ Result ] The contents of three kinds of insecticides in two media gradually declined with the prolongation of time, and degradation rates presented the trend of fast-slow-fast ; the degradation rates of permethrin, cyfluthrin and c/s-cypermethrin in cut tobacco at 36 d post ad- ministration were 97.14%, 88.89% and 95.38%, respectively; the degradation rates on iron sheet surface were 29.95%, 48.99% and 40. 24%, respectively. The half lives of three kinds of insecticides in cut tobacco were 1 -2 d, while those on iron sheet surface were 6 - 10 d. [ Conclusion] The contents of three kinds of insecticides in two media gradually declined with the prolongation of time, and their degradation regularity accorded with first order kinetic equation.
[ Objective] In order to provide a reference for safe and reasonable use of pyrethroids in cigarette production, the degradation behaviors of three kinds of pyrethroids in cigarette production environment were studied. [ Method ] Three kinds of pyrethroids （permethrin, cyfluthrin and c/s-cypermethrin） were adminis- trated to two media （cut tobacco and iron sheet surface） in cigarette production environment at MRLs concentration, and the first sampling was conducted at 24 d post administration. Afterwards, sampling was performed once every 7 d, with a total of six times. The degradation rates of insecticides in different media were cal- culated, and degradation models were established. [ Result ] The contents of three kinds of insecticides in two media gradually declined with the prolongation of time, and degradation rates presented the trend of fast-slow-fast ; the degradation rates of permethrin, cyfluthrin and c/s-cypermethrin in cut tobacco at 36 d post ad- ministration were 97.14%, 88.89% and 95.38%, respectively; the degradation rates on iron sheet surface were 29.95%, 48.99% and 40. 24%, respectively. The half lives of three kinds of insecticides in cut tobacco were 1 -2 d, while those on iron sheet surface were 6 - 10 d. [ Conclusion] The contents of three kinds of insecticides in two media gradually declined with the prolongation of time, and their degradation regularity accorded with first order kinetic equation.
基金
Supported by Standard Project of State Tobacco Monopoly Administration(2014B023)
