摘要
脂肪胺是人类生活和化学工业中重要的中间体,醇的氨解是制备脂肪胺的主要方法,当脂肪族卤代烃廉价易得时,也可以使用脂肪卤代烃的氨解反应来制备各种脂肪胺。综述了近年来脂肪族卤代烃与氨、胺和其它含氮化合物的氨解反应的研究进展,并对德尔宾反应和盖布瑞尔反应进行了简介。
Fatty amines are very important intermediates in human life and the chemical industry. The am- monolysis of alcohol is primary method for preparing fatty amine compounds, and ammonolysis of aliphatic halo- genated hydrocarbons is also used when the hydrocarbons are cheap and facile. The recent progress in ammonoly- sis of aliphatic halogenated hydrocarbons with ammonia, amines and other nitrogen-containing compounds is re- viewed, and Del6pine reaction and Gabriel reaction are surveyed.
出处
《化学工程师》
CAS
2016年第11期52-56,共5页
Chemical Engineer
基金
陕西省科技统筹创新工程计划项目(2015KTCL01-16)
关键词
脂肪胺
脂肪族卤代烃
氨解
进展
fatty amine
aliphatie halogenated hydrocarbon
ammonolysis
progress
