低解吸气量页岩气组分校正方法探讨

Discussion on components content correction of shale gas with low desorption gas quantity

通过现场解吸试验,采用气相色谱等测试方法,对低解吸气量页岩气组分测定结果校正方法进行了研究.在常规现场解吸试验操作基础上增加校正实验,结合理想气体状态方程,总结归纳出校正参数及适用性研究.结果显示,当解析气量较少时,解吸罐内残留空气对组分测定结果的影响较大,排除解吸罐中空气的影响后,解吸气组分甲烷体积分数普遍增加12.23%-54.44%.研究表明,对低解吸气量页岩气组分结果进行校正十分必要.

With the method of field desorption and gas chromatography,the components content correction of shale gas with low desorption gas quantity was studied. Correction experiment was added besides normal field desorption experiments,and ideal gas state equation was also used to seek the correction parameters and their suitability. The results showed that the residual air within the desorption canister had a great effect on components content when desorption gas content is low. Volume fraction of methane will increase about 12. 23 %- 54. 44 % generally if the residual air can be excluded. It is thus necessary that the components content of shale gas with low desorption gas quantity should be corrected.