新型N-杂环卡宾研究进展

Research Advances of New N-heterocyclic Carbene

近20年来,N-杂环卡宾已经成为有机化学研究领域的明星分子。随着研究不断深入,各种新型N-杂环卡宾被合成出来。结合N-杂环卡宾的相关研究报道,简要介绍了经典N-杂环卡宾(1,3-二取代咪唑卡宾)的基本情况,随后重点介绍了反常N-杂环卡宾和其他新型N-杂环卡宾的合成和研究情况。在此基础上,指出了今后N-杂环卡宾合成研究的发展方向。

N-heterocyclic carbene has become a star in the field of organic chemistry research,over the past 20 years. A number of new N-heterocyclic carbenes have been synthesized,while the research is developing. According to the recent reports,the classic N-heterocyclic carbene（ 1,3-disubstituted imidazole carbene） was briefly introduced,firstly. The recent research advances of abnormal N- N-heterocyclic carbene and other novel N-heterocyclic carbene were focused on. The development trends of N-heterocyclic carbine synthesis and research were proposed,on the basis.