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Synthesis and characterization of silsesquioxane-cored star-shaped hybrid polymer via "grafting from" RAFT polymerization 被引量:3

Synthesis and characterization of silsesquioxane-cored star-shaped hybrid polymer via "grafting from" RAFT polymerization
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摘要 Organic/inorganic hybrid polymers have been widely studied for their potential use in nanocontainers and nanocarriers. In this article, one star-shaped hybrid polymer, polyhedral oligomeric silsesquioxane (POSS) grafted poly(N,N-(dimethylamino)ethyl methacrylate) (POSS-g-PDMA), was synthesized via reversible addition-fragmentation chain transfer polymerization (RAFT). The pH stimuli-responsive character of POSS-g-PDMA in aqueous solution were also studied. Organic/inorganic hybrid polymers have been widely studied for their potential use in nanocontainers and nanocarriers. In this article, one star-shaped hybrid polymer, polyhedral oligomeric silsesquioxane (POSS) grafted poly(N,N-(dimethylamino)ethyl methacrylate) (POSS-g-PDMA), was synthesized via reversible addition-fragmentation chain transfer polymerization (RAFT). The pH stimuli-responsive character of POSS-g-PDMA in aqueous solution were also studied.
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 2016年第11期1696-1700,共5页 中国化学快报(英文版)
基金 supported by the Guangdong Province Research Project(No.2011A091000007) the National Natural Science Foundation of China for its financial support(No.21174162)
关键词 Star-polymer RAFT POSS Graft from Stimuli-responsive Star-polymer RAFT POSS Graft from Stimuli-responsive
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