有机三价碘试剂在杂环化合物合成中的应用进展

Recent Advances of the Application of Organoiodine (Ⅲ) Reagents in the Construction of Heterocyclic Compounds

高价碘化学在过去的30年间经历了突飞猛进的发展.作为一类温和、高效、环境友好的非金属氧化试剂,高价碘化合物尤其是有机三价碘试剂被广泛应用于各种杂环化合物骨架的构建中.综述了有机三价碘试剂介导下不同环系杂环化合物合成的新策略及新方法.

Hypervalent iodine chemistry has experienced explosive development over the past 30 years. Being a class of mild, efficient and environmentally benign nonmetal oxidants, hypervalent iodine regents, especially iodine（Ⅲ） oxidants have been widely applied to the construction of various heterocyelic skeletons. In this review, the iodine（Ⅲ）-mediated strategies and methods for the synthesis of heterocyclic compounds with different ring size were highlighted.