碘催化芳基磺酰氯与富电子化合物的硫醚化反应

Iodine Catalyzed Thiolation of Electron Rich Compounds with Benzenesulfonyl Chlorides

报道了在单质碘的催化下,以三苯基膦作为还原剂,通过芳基磺酰氯与各类富电子化合物的硫醚化反应,合成多种含硫化合物的方法.该方法具有较广的底物普适性,原料来源广泛、易得,操作简便以及反应高效等优点.

Iodine catalyzed thiolation of various electron rich compounds using extensive source benzenesulfonyl chlorides as a sulfur source in presence of PPh3 as a reducing agent. The advantages of the present protocol include operational conven- ience, high efficiency and wide-application.