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Tunable Synthesis of Core-shell a-Fe2O3/TiO2 Composite Nanoparticles and Their Visible-light Photocatalytic Activity

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摘要 Uniform a-Fe203/amorphous TiO2 core-shell nanocomposites were prepared via a hydrolysis method anda-Fe2OJanatase TiO2 core-shell nanocomposites were obtained via a post-calcination process. The structure andmorphology of the products were characterized by powder X-ray diffraction, X-ray photoelectron spectroscopy,transmission electron microscopy and scanning electron microscopy. Amorphous TiO2 nanoparticles with diametersof ten to several tens nanometer were formed on the surface of a-Fe203 nanoparticles and the coverage density of thesecondary TiO2 nanoparticles in the composite can be controlled by varying the concentration of Ti(BuO)4 m theethanol solution. The visible-light photocatalytic properties of different products towards Rhodamine B(RhB) wereinvestigated. The results show that the a-Fe203/amorphous TiO2 exhibits a good photocatalytic property owing to theextension of the light response range to visible light and the efficient separation of photogenerated electrons and holesbetween a-Fe203 and amorphous TiO2.
出处 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2016年第6期882-888,共7页 高等学校化学研究(英文版)
分类号 O [理学]
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