摘要
The evolution of Cr23C6 carbides in the deposited metal （DM） of a high-chromium nickel-based alloy was investigated after the post-weld heat treatment （PWHT） at 650, 750, 850, and 950 ℃, respectively. With the increase in temperature, the morphology of the Cr23C6 carbides at the grain boundaries was transformed from the continuous lamellar- like to the semi-continuous rod-like and then to the discontinuous granular. Besides, the needle-like Cr23C6 carbides precipitated from 7 matrix after PWHT at 850 ℃. The coarsening kinetics of the needle-like Cr23C6 carbides obeyed the Lifshitz-Slyozov-Wagner law with the growth speed of 4.93 μm3/h in length and 5.56 ×10^-3 μm3/h in width. Moreover, the ratio of the carbide length to width increased rapidly at first and then flattened as the holding time increased to 850 ℃. The results of electrochemical corrosion experiment indicated that the needled-like Cr23C6 carbides impaired the corrosion resistance of DM due to the formation of chromium depletion around the carbides.
The evolution of Cr23C6 carbides in the deposited metal （DM） of a high-chromium nickel-based alloy was investigated after the post-weld heat treatment （PWHT） at 650, 750, 850, and 950 ℃, respectively. With the increase in temperature, the morphology of the Cr23C6 carbides at the grain boundaries was transformed from the continuous lamellar- like to the semi-continuous rod-like and then to the discontinuous granular. Besides, the needle-like Cr23C6 carbides precipitated from 7 matrix after PWHT at 850 ℃. The coarsening kinetics of the needle-like Cr23C6 carbides obeyed the Lifshitz-Slyozov-Wagner law with the growth speed of 4.93 μm3/h in length and 5.56 ×10^-3 μm3/h in width. Moreover, the ratio of the carbide length to width increased rapidly at first and then flattened as the holding time increased to 850 ℃. The results of electrochemical corrosion experiment indicated that the needled-like Cr23C6 carbides impaired the corrosion resistance of DM due to the formation of chromium depletion around the carbides.
