期刊文献+

含氮试剂对活性炭掺杂改性研究

Preparation of Nitrogen Doped Activated Carbon
下载PDF
导出
摘要 多孔炭材料经过含氮试剂的掺杂改性后,宏观及微观性能都发生显著变化,在具有高比表面积、优良的耐热、耐酸碱的同时,还具有独特的电子传导性和催化性能,使其具有更广阔的应用前景。通过含氮试剂对活性炭改性制备考察,运用扫描电镜(SEM)、傅里叶变换红外光谱(FT-IR)、元素分析、BET氮吸附法对活性炭改性前后氮含量、表面官能团和孔结构变化进行表征分析,研究结果显示三聚氰胺、二氰二胺改性效果优异其他改性试剂。 Abstract: After containing nitrogen reagent of doping modification, macroscopic and microscopic properties of porous carbon materials have occur significant changes,it has high specific surface area,excellent heat resistance,acid and alkali resistance and unique electronic conductivity and catalytic properties,which has a wider application prospect. The activated carbon modified system were investigated by containing nitrogen reagent, the modification of activated carbon and nitrogen content, surface functional groups and pore structure changes were characterized and analyzed using scanning electron microscopy( SEM),Fourier transform infrared spectrometer( FT-IR),elemental analysis and BET nitrogen adsorption. The results showed that melamine and dicyandiamide modified effect was superior to other modification reagent.
作者 王聚恒 刘见祥 张怡 黄晓枭 WANG Ju-heng LIU Jian-xiang ZHANG Yi HUANG Xiao-xiao(Guizhou Institute of Metallurgy and Chemical Engineering, Guizhou Guiyang 550002 Nanometer Marerial Engineering Center of Guizhou, Guizhou Guiyang 550002, China)
出处 《广州化工》 CAS 2017年第1期47-50,共4页 GuangZhou Chemical Industry
基金 贵州省科技计划项目 贵州科学院青年基金项目(黔科院J合字[2014]16号)
关键词 活性炭 氮含量 氮掺杂多孔材料 activated carbon nitrogen content nitrogen doped porous materials
  • 相关文献

参考文献3

二级参考文献42

  • 1魏惠民.合成氯乙烯用催化剂的制备方法:中国,063827A[P].1992-08-26.
  • 2王绪根,代斌.载体对乙炔氢氯化低汞催化剂性能的影响[C/CD]∥中国化学会催化专业委员会.第十五届全国催化学术会议论文集,2010,PF-026.
  • 3王良栋.氯化汞低汞催化剂及其制备方法:中国,CN101596459[P].2009-12-09.
  • 4Boehm H P. Some aspects of the surface chemistry of carbon black and other carbons[J]. Carbon , 1994,32:759-769.
  • 5Joong S N, Schwarz J A. Effect of HNO3 treatment on the surface acidity of activated carbons [J].Carbon, 1990,28 (5) : 675-682.
  • 6Chiang H L, Huang C P, Chiang P C. Effect of metal additives on the physico-chemical characteristics of activated carbon exemplified by benzene and acetic acid[J]. Carbon, 1999, 37:1919-1928.
  • 7Moreno-Castilla C, Carrasco-Marin F, Mueden A.The creation of carbon surfaces by treatment with (NH4)2S2O8[J]. Carbon,35(10):1619-1626 .
  • 8Fanning P E, Vannic M A. A drifts study of surface groups on carbon by oxidation[J]. Carbon, 1993,31(5) : 721-730.
  • 9Painter P, Starsinic M ,Coleman M. Determination of functional groups in coal by Fourier transform interferometry [J]. Fourier transform infrared spectrosocopy, 1985,4 : 168-189.
  • 10Zhou X G,Yu X Q, Huang J S, et al. Asymmetric epoxidation of alkenes catalysed by chromium binaphthyl Schiff base complex supported on MCM-41 [ J]. Chem Commun. 1999,19: 1789- 1790.

共引文献72

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部