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Synthesis and Properties of a Novel 3D Europium Coordination Polymer with Helical Chain and (3,6)-Connected rtl Net

Synthesis and Properties of a Novel 3D Europium Coordination Polymer with Helical Chain and (3,6)-Connected rtl Net
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摘要 The first coordination polymer of 2,2'-((4-carboxymethyl-1,3-phenylene)bis(oxy)) diacetic acid (H3L) with eu- ropium([II) ion, [Eu(L)(H2O)]'3H2O (1), has been hydrothermally synthesized and structurally characterized. Complex 1 exhibits a 3D coordination polymer with helical chain and rtl topology of the point symbol (4·6^2)2(4^2·6^10·8^3) based on [Eu2(COO)4] as secondary building unit (SBU). Furthermore, the luminescent and magnetic properties of complex 1 are studied. The first coordination polymer of 2,2'-((4-carboxymethyl-1,3-phenylene)bis(oxy)) diacetic acid (H3L) with eu- ropium([II) ion, [Eu(L)(H2O)]'3H2O (1), has been hydrothermally synthesized and structurally characterized. Complex 1 exhibits a 3D coordination polymer with helical chain and rtl topology of the point symbol (4·6^2)2(4^2·6^10·8^3) based on [Eu2(COO)4] as secondary building unit (SBU). Furthermore, the luminescent and magnetic properties of complex 1 are studied.
出处 《Chinese Journal of Chemistry》 SCIE CAS CSCD 2016年第12期1304-1308,共5页 中国化学(英文版)
关键词 europium coordination polymer HELIX topological structure LUMINESCENCE MAGNETISM europium coordination polymer, helix, topological structure, luminescence, magnetism
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