摘要
The first coordination polymer of 2,2'-((4-carboxymethyl-1,3-phenylene)bis(oxy)) diacetic acid (H3L) with eu- ropium([II) ion, [Eu(L)(H2O)]'3H2O (1), has been hydrothermally synthesized and structurally characterized. Complex 1 exhibits a 3D coordination polymer with helical chain and rtl topology of the point symbol (4·6^2)2(4^2·6^10·8^3) based on [Eu2(COO)4] as secondary building unit (SBU). Furthermore, the luminescent and magnetic properties of complex 1 are studied.
The first coordination polymer of 2,2'-((4-carboxymethyl-1,3-phenylene)bis(oxy)) diacetic acid (H3L) with eu- ropium([II) ion, [Eu(L)(H2O)]'3H2O (1), has been hydrothermally synthesized and structurally characterized. Complex 1 exhibits a 3D coordination polymer with helical chain and rtl topology of the point symbol (4·6^2)2(4^2·6^10·8^3) based on [Eu2(COO)4] as secondary building unit (SBU). Furthermore, the luminescent and magnetic properties of complex 1 are studied.