有机碳源作用下厌氧氨氧化系统的脱氮效能

Nitrogen Removal Performance of ANAMMOX with Different Organic Carbon Sources

采用ASBR厌氧氨氧化反应器,研究不同有机碳源及浓度变化对厌氧氨氧化菌活性与反应器脱氮性能的影响.实验结果表明,当葡萄糖浓度为200 mg·L^(-1)时,厌氧氨氧化活性下降84.2%;当乙酸钠浓度低于120 mg·L^(-1)时不但不会抑制厌氧氨氧化菌的活性,还在一定程度上促进了厌氧氨氧化反应的进行;蔗糖对厌氧氨氧化的促进作用与乙酸钠类似,当浓度为80mg·L^(-1)时,最大比厌氧氨氧化速率提高了25.0%;柠檬酸三钠对厌氧氨氧化反应几乎没有影响,当有机物浓度为80 mg·L^(-1)时,最大比厌氧氨氧化速率达到最大.有机碳源对厌氧氨氧化的促进作用由大到小为:蔗糖>乙酸钠>柠檬酸三钠>葡萄糖.有机碳源作用下,厌氧氨氧化反应可协同反硝化反应去除系统中的硝态氮,提高了系统总氮的去除率.

Anaerobic ammonium oxidation （ANAMMOX） has been regarded as an efficient process to treat high-strength wastewater without organic carbon source. To investigate the nitrogen removal performance of ANAMMOX in the presence of organic carbon source can broaden its application in organic wastewater treatment. In this work, an anaerobic sequencing batch reactor （ASBR） was used to study the effect of organic carbon source on ANAMMOX process. The experimental results indicated that the activity of anaerobic ammonia oxidizing bacteria （AAOB） decreased by 84. 2% when 200 mg·L ^- 1 COD of glucose was added. When sodium acetate was added, the activity of AAOB was affected little. Besides, it even promoted the activity with COD less than 120 mg·L ^- 1 . The effect of sucrose on ANAMMOX process was similar to that of sodium acetate and the maximum specific ANAMMOX activity （SAA） increased by 25. 0% with 80 mg·L^ - 1 COD. When citric acid was added, the maximum SAA peaked with 80 mg·L ^- 1 COD. The order of ANAMMOX promotion resulted from organic carbon source was sucrose, sodium acetate, citric acid and glucose. With addition of organic carbon source, nitrate could also be removed through the synergy of ANAMMOX and denitrification, and the total nitrogen removal efficiency increased.