摘要
An efficient and broadly applicable protocol for the aerobic coupling of styrenes with sulfonylhydrazides has been developed that affords P-ketosulfones bearing various functional groups in moderate to excellent yields.The preliminary experimental results support the involvement of active benzyl radical species,and a radical pathway was therefore proposed for the reaction.
An efficient and broadly applicable protocol for the aerobic coupling of styrenes with sulfonylhydrazides has been developed that affords P-ketosulfones bearing various functional groups in moderate to excellent yields.The preliminary experimental results support the involvement of active benzyl radical species,and a radical pathway was therefore proposed for the reaction.
基金
supported by the National Natural Science Foundation of China(U1504210)
the China Postdoctoral Science Foundation funded project(2015M572110)
Jilin Province Key Laboratory of Organic Functional Molecular Design & Synthesis(130028651)
