摘要
Three different castables were prepared as steel-ladle purging-plug refractory materials： corundum-based low-cement castable （C-LCC）, corundum-spinel-based low-cement castable （C-S-LCC）, and no-cement corundum-spinel castable （C-S-NCC） （hydratable alu- mina p-A1203 bonded）. The properties of these castables were characterized with regard to water demand/flow ability, cold crushing strength （CCS）, cold modulus of rupture （CMoR）, permanent linear change （PLC）, apparent porosity, and hot modulus of rupture （HMoR）. The re- sults show the CCS/CMoR and HMoR of C-LCC and C-S-LCC are greater than those of the castable C-S-NCC. According to the micro- structure analysis, the sintering effect and the bonding type of the matrix material differ among the three castables. The calcium hexaluminate （CA6） phase in the matrix of C-LCC enhances the cold and hot mechanical strengths. In the case of C-S-LCC, the CA6 and 2CaO·2MgO·14A12O3（C2MEA14） ternary phases generated from the matrix can greatly increase the cold and hot mechanical strengths. In the case of the no-cement castable, sintering becomes difficult, resulting in a lower mechanical strength.
Three different castables were prepared as steel-ladle purging-plug refractory materials： corundum-based low-cement castable （C-LCC）, corundum-spinel-based low-cement castable （C-S-LCC）, and no-cement corundum-spinel castable （C-S-NCC） （hydratable alu- mina p-A1203 bonded）. The properties of these castables were characterized with regard to water demand/flow ability, cold crushing strength （CCS）, cold modulus of rupture （CMoR）, permanent linear change （PLC）, apparent porosity, and hot modulus of rupture （HMoR）. The re- sults show the CCS/CMoR and HMoR of C-LCC and C-S-LCC are greater than those of the castable C-S-NCC. According to the micro- structure analysis, the sintering effect and the bonding type of the matrix material differ among the three castables. The calcium hexaluminate （CA6） phase in the matrix of C-LCC enhances the cold and hot mechanical strengths. In the case of C-S-LCC, the CA6 and 2CaO·2MgO·14A12O3（C2MEA14） ternary phases generated from the matrix can greatly increase the cold and hot mechanical strengths. In the case of the no-cement castable, sintering becomes difficult, resulting in a lower mechanical strength.
