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基于四羟甲基甘脲前驱体的新型含氮富微孔活性炭制备及其性能研究 被引量:1

Study on Synthesis and Electrochemical Behavior of New Nitrogen-enriched Microporous Carbon Based on Tetramethylol Acetylenediurea
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摘要 以四羟甲基甘脲为碳前驱体,采用KOH活化法处理得到双电层电容器用多孔活性炭材料。考察了不同碳化、活化温度对活性炭比电容的影响。结果表明,在850℃碳化,650℃活化处理时其电容性能最好,SEM和比表面与孔径分布测试说明TA-850-650表面富集微孔;恒流充放电与循环伏安测试结果表明TA-850-650的比电容在电流密度为0.2A/g时可达527F/g。 The porous carbon,prepared from tetramethylol acetylenediurea by activation of KOH,were applied in electric double-layer capacitor(EDLC).The carbonization and activated temperature had a significant influence both on porosity structure and electrochemical performances.Results showed that the micropores enriched on the surface of TA-850-650.The specific capacitance of TA-850-650 could reach 527F/g at 0.2A/g.
作者 黄凯兵 杨秀文 王智健 姚异渊 HUANG Kaibing YANG Xiuwen WANG Zhijian YAO Yiyuan(College of Material Science and Engineering, Hunan University, Changsha 410082)
出处 《材料导报》 EI CAS CSCD 北大核心 2017年第4期30-35,共6页 Materials Reports
关键词 四羟甲基甘脲 双电层电容器 活化温度 微孔 比电容 tetramethylol acetylenediurea electric double-layer capacitor(EDLC) activated temperature micro-porosity specific capacitance
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  • 1松村雄次.超级活性炭的开发[J].化学与工业,1990,43(3):358-358.
  • 2西野敦.用活性炭纤维制备的双层电容器[J].炭素,1988,132:57-57.
  • 3江奇 卢晓英 等.碳纳米管电化学超级电容器性能初探.第五届全国新型碳材料学术研讨会论文集[M].-,2001,10.371.
  • 4CONWAY BE. Electrochemical supercapacitors-scientific fundamentals and technological applications [M]. New York: Kluwer/Plenum Press, 1999: 13-21.
  • 5ZHANG L L, ZHAO X S. Carbon-based materials as supercapacitor electrodes [J]. Chem Soc Rev, 2009, 38, 2520-2531.
  • 6WANG D W, LI F, LIU M, et al. 3D aperiodic hierarchical porous graphitic carbon material for high-rate electrochemical capacitive energy storage [J]. Angew Chem Int Ed, 2008, 47(2): 373-376.
  • 7ALONSO A, RUIZ V, BLANCO C, et al. Activated carbon produced from Sasol-Lurgi gasifier pitch and its application as electrodes in supercapacitors [J]. Carbon, 2006, 44: 441-446.
  • 8J]N X J, ZHANG M Y, WU Y, et al. Nitrogen-enriched waste medium density fiberboard-based activated carbons as materials for supercapacitors [J]. Ind Crops Prod, 2013, 43: 617-622.
  • 9AN K H, KIM W S, PARK Y S, et al. Supercapacitors using single-walled carbon nanotubes electrodes [J]. Adv Mater, 2001, 13(7): 497-500.
  • 10SHA[JUMON M M, OU F S, CI L J, et al. Synthesis of hybrid nanowire arrays and their application as high power supercapacitor electrodes [J]. Chem Commun, 2008, 2373-2375.

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