在含氮杂环上引入硝基的方法

The Methods for Introducing Nitro Group to Nitrogen-containing Heterocycles

硝基是含能材料的重要爆炸基团,可显著提高含能材料的爆轰性能。在含氮杂环上引入硝基的常见方法,包括直接硝化法、重氮化硝基取代法、氨基氧化法等,通过综述这些方法以及每种方法所用到的反应体系、部分含能材料的特性,为新型硝基含氮杂环化合物的合成提供参考。

As an important moiety, the nitro group would remarkably improve detonation performance of energetic materials. Commonly used methods for introducing nitro group to nitrogen-containing heterocycles include nitration, diazotization-Substitute of nitro, oxidation of amino, etc. It offers experimental support for the synthesis of novel nitro-containing energetic materials by reviewing these methods and the corresponding reaction systems and properties of some energetic products.