摘要
测定了丁腈橡胶(NBR)/无机金属盐配位聚合物体系的参数:NBR的分子量、NBR的溶解度参数和无限稀释摩尔电导率、配位体系的配位数.结果表明,NBR与无机金属盐发生了配位交联,NBR/CuCl_2配位聚合物的配位数为4,NBR/LaCl_3配位聚合物的配位数为8.
Parameters of Nitrile Butadience Rubber（ NBR） / inorganic metallic salt coordination polymer system were determined： molecular weight of NBR,solubility parameter and molar conductivity at infinite dilution of NBR,coordination number of the coordination polymer. The results showed that coordination crosslinking reaction has happened between NBR and inorganic metallic salt. The coordination number of NBR / CuCl2 coordination polymer is 4 and the coordination number of NBR / LaCl3 coordination polymer is 8.
作者
卓倩
孔飞
杨文卿
许丽洪
陈庆华
ZHUO Qian KONG Fei YANG Wen-qing XU Li-hong CHEN Qing-hua(The College of Minnan Science and Technology, The College of Environmental Science and Engineering, Fujian Normal University, Fuzhou 362332, China Institute of Environmental Sciences, College of Minnan Science and Technology, Quanzhou 362332, China Institute of Fujian Modified Plastic Research and Develop Technology, Fuzhou 350007, China)
出处
《福建师范大学学报（自然科学版）》
CAS
CSCD
北大核心
2017年第2期44-49,共6页
Journal of Fujian Normal University：Natural Science Edition
基金
福建省高校企业重大项目(2013H6007)
福建省教育厅中青年项目(JAT160672)
关键词
无机金属盐
丁腈橡胶
配位数
inorganic metallic salt
Nitrile Butadience Rubber（NBR）
coordination number
