过渡金属催化P—C键偶联反应的研究进展

Recent Advances of Transition Metal-Catalyzed P—C Coupling Reactions

含有P—C键的有机膦化合物在光电、阻燃材料以及药物化学等研究领域具有广泛的应用.通过过渡金属催化P(O)—H化合物的交叉偶联构建P—C键是合成功能有机膦化合物的重要方法.按碳原子的不同杂化类型分类,对此类反应的研究进展进行了综述.

Organophosphorus compounds which contain P-C bonds have been widely used in photoelectric materials, retardant materials and medicinal chemistry. It is an important method for the synthesis of functional organophosphorus compounds from P（O）-H reagents using transition metal-catalyzed cross coupling reaction to form P-C bond. The recent development in this area is summarized on the basis of different types of carbon atom.