摘要
Titanium dioxide (TiO2) loaded tungsten trioxide (WO3) composite films are prepared by an E-beam vapor system. Associated with the existence of a heterojunction at the interface of TiO2 and WO3, the prepared TiO2-WO3 composite film shows enhanced photocurrent density, four times than the pure WO3 film illuminated under xenon lamp, and higher incident-photon-to-current conversion e^ciency. By varying the initial TiO2 film thickness, such composite structures could be optimized to obtain the highest photocurrent density. We believe that thin TiO2 films improve the light response and increase the surface roughness of WO3 films. Furthermore, the existence of the heterojunction results in the e^cient charge carriers' separation, transfer process, and a lower recombination of electron-hole pairs, which is beneficial for the enhancement of photocurrent density.
Titanium dioxide (TiO2) loaded tungsten trioxide (WO3) composite films are prepared by an E-beam vapor system. Associated with the existence of a heterojunction at the interface of TiO2 and WO3, the prepared TiO2-WO3 composite film shows enhanced photocurrent density, four times than the pure WO3 film illuminated under xenon lamp, and higher incident-photon-to-current conversion e^ciency. By varying the initial TiO2 film thickness, such composite structures could be optimized to obtain the highest photocurrent density. We believe that thin TiO2 films improve the light response and increase the surface roughness of WO3 films. Furthermore, the existence of the heterojunction results in the e^cient charge carriers' separation, transfer process, and a lower recombination of electron-hole pairs, which is beneficial for the enhancement of photocurrent density.
作者
王文桂
朱丽
翁雨燕
董雯
Wen-Gui Wang Li Zhu Yu-Yan Weng Wen Dong(College of Physics, Optoelectronics and Energy, Collaborative Innovation Center of Suzhou Nano Science and Jiangsu Key Laboratory of Thin Films, Soochow University, Suzhou 215006)
基金
Supported by the National Natural Science Foundation of China under Grant Nos 11174137,11474215 and 21204058
the Natural Science Foundation for the Youth of Jiangsu Province under Grant No BK20130284
the Priority Academic Program Development of Jiangsu Higher Education Institutions