摘要
TiO2 films have been widely applied in photo- voltaic conversion techniques. TiO2 nanotube arrays (TiO2 NAs) can be grown directly on the surface of metal Ti by the anodic oxidation method. Bi2S3 and PbS nanoparticles (NPs) were firstly co-sensitized on TiOa NAs (denoted as PbS/Bi2S3(n)/TiO2 NAs) by a two-step process containing hydrothermal and sonication-assisted SILAR method. When the concentration of Bi3+ is 5 mmol/L, the best photoelectrical performance was obtained under simulated solar irradiation. The short-circuit photocurrent (Jsc) and photoconversion efficiency (η) of PbS/Bi2S3(5)/TiO2 NAs electrode were 4.70 mA/cm and 1.13 %, respectively.
TiO2 films have been widely applied in photo- voltaic conversion techniques. TiO2 nanotube arrays (TiO2 NAs) can be grown directly on the surface of metal Ti by the anodic oxidation method. Bi2S3 and PbS nanoparticles (NPs) were firstly co-sensitized on TiOa NAs (denoted as PbS/Bi2S3(n)/TiO2 NAs) by a two-step process containing hydrothermal and sonication-assisted SILAR method. When the concentration of Bi3+ is 5 mmol/L, the best photoelectrical performance was obtained under simulated solar irradiation. The short-circuit photocurrent (Jsc) and photoconversion efficiency (η) of PbS/Bi2S3(5)/TiO2 NAs electrode were 4.70 mA/cm and 1.13 %, respectively.
基金
supported by Program of International S&T Cooperation(2013 DFA51050)
National Magnetic Confinement Fusion Science Program(2013GB110001)
the 863Program(2014AA032701)
the National Natural Science Foundation of China(11405138,51302231)
the Western Superconducting Technologies Co.,Ltd