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Ablation Mechanism of Carbon/Carbon Composites Modified by HfC–SiC in Two Conditions Under Oxyacetylene Torch

Ablation Mechanism of Carbon/Carbon Composites Modified by HfC–SiC in Two Conditions Under Oxyacetylene Torch
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摘要 C/C-HfC-SiC composites prepared by precursor infiltration and pyrolysis process were ablated by oxyacetylene torch under two different flame conditions. The ablation performance of the composites was investigated in the heat flux of 2.38 MW/m2 (HF-L) and 4.18 MW/m2 (HF-H) for 60 s. The mechanical denudation in 4.18 MW/m2 (HF-H) was higher than that in 2.38 MW/m2 (HF-L), while the results indicated that the composites had a similar and good ablation property under two different flame conditions. C/C- HfC-SiC composites can adapt the heat flux from 2.38 MW/m2 to 4.18 MW/m2. The Hf02 was not melted completely in the heat flux of 2.38 MW/m2 (HF-L). So, both Hf02 and Si02 layers acted as an effective barrier to the transfer of heat and oxidative gases into the underlying carbon substrate. SiO2 was severely consumed in 4.18 MW/m2 (HF-H), where the HfO2 molten layer played a more important role in protecting the inner composite. C/C-HfC-SiC composites prepared by precursor infiltration and pyrolysis process were ablated by oxyacetylene torch under two different flame conditions. The ablation performance of the composites was investigated in the heat flux of 2.38 MW/m2 (HF-L) and 4.18 MW/m2 (HF-H) for 60 s. The mechanical denudation in 4.18 MW/m2 (HF-H) was higher than that in 2.38 MW/m2 (HF-L), while the results indicated that the composites had a similar and good ablation property under two different flame conditions. C/C- HfC-SiC composites can adapt the heat flux from 2.38 MW/m2 to 4.18 MW/m2. The Hf02 was not melted completely in the heat flux of 2.38 MW/m2 (HF-L). So, both Hf02 and Si02 layers acted as an effective barrier to the transfer of heat and oxidative gases into the underlying carbon substrate. SiO2 was severely consumed in 4.18 MW/m2 (HF-H), where the HfO2 molten layer played a more important role in protecting the inner composite.
出处 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2017年第1期71-78,共8页 材料科学技术(英文版)
基金 supported by the National Natural Science Foundation of China(Grant Nos.51072166 and 51472202) by the Program of Introducing Talents of Discipline to University(Grant No.B08040)
关键词 Carbon/carbon composites CORROSION Ablation performance Carbon/carbon composites Corrosion Ablation performance
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