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Pore characterization of different types of coal from coal and gas outburst disaster sites using low temperature nitrogen adsorption approach 被引量:15

Pore characterization of different types of coal from coal and gas outburst disaster sites using low temperature nitrogen adsorption approach
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摘要 To characterize the pore features of outburst coal samples and investigate whether outburst coal has some unique features or not, one of the authors, working as the member of the State Coal Mine Safety Committee of China, sampled nine outburst coal samples(coal powder and block) from outburst disaster sites in underground coal mines in China, and then analyzed the pore and surface features of these samples using low temperature nitrogen adsorption tests. Test data show that outburst powder and block coal samples have similar properties in both pore size distribution and surface area. With increasing coal rank, the proportion of micropores increases, which results in a higher surface area. The Jiulishan samples are rich in micropores, and other tested samples contain mainly mesopores, macropores and fewer micropores. Both the unclosed hysteresis loop and force closed desorption phenomena are observed in all tested samples. The former can be attributed to the instability of the meniscus condensation in pores,interconnected pore features of coal and the potential existence of ink-bottle pores, and the latter can be attributed to the non-rigid structure of coal and the gas affinity of coal. To characterize the pore features of outburst coal samples and investigate whether outburst coal has some unique features or not, one of the authors, working as the member of the State Coal Mine Safety Committee of China, sampled nine outburst coal samples(coal powder and block) from outburst disaster sites in underground coal mines in China, and then analyzed the pore and surface features of these samples using low temperature nitrogen adsorption tests. Test data show that outburst powder and block coal samples have similar properties in both pore size distribution and surface area. With increasing coal rank, the proportion of micropores increases, which results in a higher surface area. The Jiulishan samples are rich in micropores, and other tested samples contain mainly mesopores, macropores and fewer micropores. Both the unclosed hysteresis loop and force closed desorption phenomena are observed in all tested samples. The former can be attributed to the instability of the meniscus condensation in pores,interconnected pore features of coal and the potential existence of ink-bottle pores, and the latter can be attributed to the non-rigid structure of coal and the gas affinity of coal.
出处 《International Journal of Mining Science and Technology》 SCIE EI CSCD 2017年第2期371-377,共7页 矿业科学技术学报(英文版)
基金 provided by the Fundamental Research Funds for the Universities of Henan Province of China(No.NSFRF140105) the 2015 Key Research Program of Higher Education Institution in Henan Department of Education of China(No.15A440007) the Henan Polytechnic University Doctoral Fund Project(No.B2014-004) the 2016 Foundation and Advanced Technology Research Project of Henan Province(No.162300410038) the 2014 Provincial University Training Program Under the National-Level Undergraduate Training Program in Innovation and Entrepreneurship of China(No.201410460036) the National Natural Science Foundation of China(No.51274090) the State Key Laboratory Cultivation Base for Gas Geology and Gas Control(Henan Polytechnic University-China)(No.WS2012B01)
关键词 煤与瓦斯突出 低温氮吸附法 孔隙特征 型煤 同类 地下煤矿 吸附试验 安全委员会 Outburst coal Pore Nitrogen adsorption Coal and gas outburst
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