摘要
A new low-nuclear polymolybdate cluster [Cu_4~Ⅱ（opr）_2（Mo_（12）O_（40））]_n·2n H_2 O was successfully isolated by the introduction of flexible multidentate 1,1A-（1,3-propanediyl）bis[2-（2-pyridyl）benzimidazole ligand（opr）,（NH_4）_6Mo_7O_（24）·4H_2O,and copper（Ⅱ） ions under hydrothermal conditions. Single-crystal X-ray analysis reveals that the complex crystallizes in the P2_1/n space group with a = 13.8437（5）,b =19.3953（6）,c =15.7681（6） A,β =112.698（4）o,V = 3905.9（2） A^3,Z = 4,D_c = 2.502 g/cm^3,μ = 3.020 mm^-1,F（000） = 2824,the final R = 0.0352,wR = 0.0523 and S = 0.783 for 7111 observed reflections with I 〉 2σ（I）. The structure of the compound contains a new type of low-nuclear（Mo_（12）O_（40））^8-polymolybdate cluster. These dodecamolybdate anions are linked together through sharing edges to form a 1D molybdenum oxide chain. Its photocatalytic performance for methylene blue（MB） was also studied under UV irradiation.
A new low-nuclear polymolybdate cluster [Cu_4~Ⅱ（opr）_2（Mo_（12）O_（40））]_n·2n H_2 O was successfully isolated by the introduction of flexible multidentate 1,1A-（1,3-propanediyl）bis[2-（2-pyridyl）benzimidazole ligand（opr）,（NH_4）_6Mo_7O_（24）·4H_2O,and copper（Ⅱ） ions under hydrothermal conditions. Single-crystal X-ray analysis reveals that the complex crystallizes in the P2_1/n space group with a = 13.8437（5）,b =19.3953（6）,c =15.7681（6） A,β =112.698（4）o,V = 3905.9（2） A^3,Z = 4,D_c = 2.502 g/cm^3,μ = 3.020 mm^-1,F（000） = 2824,the final R = 0.0352,wR = 0.0523 and S = 0.783 for 7111 observed reflections with I 〉 2σ（I）. The structure of the compound contains a new type of low-nuclear（Mo_（12）O_（40））^8-polymolybdate cluster. These dodecamolybdate anions are linked together through sharing edges to form a 1D molybdenum oxide chain. Its photocatalytic performance for methylene blue（MB） was also studied under UV irradiation.
基金
supported by the National Natural Science Foundation of China(No.21201128)
the Science Research Founds of Education Department of Liaoning Province(L2014596)
