摘要
利用室温扩散法合成了具有ANA型沸石分子筛拓扑结构的2-丙基咪唑镉配位聚合物2-丙基咪唑镉[Cd(pim)_2].采用单晶X射线、粉末X射线(XRD)、元素分析、热重分析(TGA)表征了该配合物的结构.结果表明[Cd(pim)_2]晶体属立方晶系,Ia-3d空间群,a=28.017 4(7)),α=90.00°,V=21 993.0(10)^(-3).
A cadmium 2-propylimidazole coordination polymer [Cd( pim)2]with topological structure of ANA zeolite molecular sieve has been synthesized under room temperature diffusion method. The compound was characterized by single-crystal X-ray analysis,powder X-ray diffraction( XRD),elemental analysis,thermal gravimetric analysis( TGA).Single crystal X-ray analysis reveals that[Cd( pim)2]crystallizes in Cubic with space group Ia-3d.a = 28.017 4( 7) ,α = 90.00°,V = 21 993.0( 10) ^-3.
出处
《吉林化工学院学报》
CAS
2017年第3期21-24,共4页
Journal of Jilin Institute of Chemical Technology
关键词
2-丙基咪唑镉
配位聚合物
晶体结构
cadmium 2-propylimidazole
coordination Polymer
crystal Structure