摘要
以癸酸(CA)、月桂酸(LA)和肉豆蔻酸(MA)为原料制备了新型的脂肪酸三元低共熔物(CA-LA-MA),并将其作为固-液相变材料,以沉积2 h银(Ag)纳米颗粒的静电纺聚丙烯腈(PAN)纳米纤维膜为支撑材料,通过物理吸附法制备了新型的CA-LA-MA/PAN和CA-LA-MA/PAN/Ag定型相变复合纤维膜。研究了磁控溅射Ag纳米层对定型相变复合纤维传热性能的影响。结果表明,沉积Ag纳米层后定型相变复合纤维膜的储热和放热时间分别缩短了31%和25%。制备的CA-LA-MA/PAN/Ag定型相变复合纤维膜的融化温度和结晶温度分别为19.87℃和11.63℃,融化焓值和结晶焓值分别为123.1 kJ/kg和121.5 kJ/kg。
A novel CA-LA-MA ternary fatty acid eutectic was firstly prepared using the three fatty acids such as capric acid (CA), laurie acid (LA), myristic acid (MA), and then was selected as solid-liquid phase-change materials (PCMs). The Ag-coated polyacrylonitrile (PAN) nanofibers membranes was selected as supporting materials to prepare the CA-LA-MA/PAN and CA-LA-MA/PAN/Ag form-stable phase change composite nanofibers membranes by physical adsorption method. The effect of coated Ag nanolayers on heat transfer rates of fom-stable phase change composite nanofibers membranes was studied in this paper. The results suggest that the melting and freezing time are respectively reduced about 31% and 25% due to coating of the Ag nanoparticles. The melting and freezing temperatures of the CA-LA-MA/PAN/Ag form-stable phase change composite nanofibers membranes are 19.87 ℃ and 11.63 ℃, respectively. And the melting and freezing enthalpies are 123.1 kJ/kg and 121.5 kJ/kg, respectively.
出处
《高分子材料科学与工程》
EI
CAS
CSCD
北大核心
2017年第4期81-86,共6页
Polymer Materials Science & Engineering
基金
福建省省属高校专项资助项目(JK2014042)
福建省科技计划项目(2015H0030)
关键词
静电纺丝
复合相变纤维
脂肪酸三元低共熔物
磁控溅射
储热性能
传热改善
electrospinning
composite phase change fibers
ternary fatty acid eutectic
magnetron sputter
thermalenergy storage properties
heat transfer improvement