二茂铁双甲酸构筑的镉配合物的合成、晶体结构和荧光性能研究

Synthesis,Structure and Luminescence Properties of Cd( II)Complexe Based on 1,1'-Ferrocenedicarboxylate

以1,1'-二茂铁双甲酸为配体,与Cd(II)作用合成了一个新配合物{[Cd(O_2CFcCO_2)_2]·CH_3CH_2OH}_n(Fc=ferrocene),并使用X-单晶衍射仪对其结构进行测试,结果发现该配合物为一维双链聚合物。对配合物的荧光性能进行了研究,数据显示该配合物的荧光性能主要取决于二茂铁双甲酸。

One new complexe { [ Cd （O2CFcCO2 ）2 ] · CH 3C H 2O H （ n （ F c = ferrocene） has been synthesized by self-assembly of ligand 1 ,1’ - Ferrocenedicarboxylate and Cd （II） cations. X - ray crystal diffraction reveals that complexe displays one - dimensional double chain structure. The fluorescence spectra of the complexe in solid state at room temperature suggest that the fluorescence emissions of the complexe is ruled by 1, 10 - ferrocenedicar-boxylate ligand.