新颖吡啶混合配体自组装配位聚合物{[Mn(4,4′-bipy)(4,4′-azpy)_2(NCS)_2].H_2O}_n的研究(英文)

Self-assembly of the novel pyridyl mixed-ligands coordination polymer {[Mn(4,4′-bipy)(4,4′-azpy)_2(NCS)_2].H_2O}_n

一个新颖配合物 { [Mn(4,4′ -bipy) (4,4′ -azpy) 2 (NCS) 2 ].H2 O} n 已经被合成 ,以及由元素分析和X -射线晶体结构所表征 ,并且进行了红外 ,紫外 ,差热分析和磁性研究 .化合物具有首次报道的三重平行插入 (4,4′)网格 。

A novel complex {[Mn(4,4′-bipy)(4,4′-azpy) 2(NCS) 2].H 2O} n (where 4,4′-bipy = 4,4′-bipyridine, 4,4′-azpy = 4,4′-azobispyridine) is synthesized and characterized by means of X ray crystal structure, elemental analyses, IR, UV, thermal properties and magnetic susceptibility. The complex has three parallel interpenetrating two dimensional (4,4) networks and form a novel infinite triple helices.