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溴染料敏化担载Pt石墨烯催化可见光制氢、氘和氦(英文) 被引量:9

Formation of Deuterium and Helium during Photocatalytic Hydrogen Generation from Water Catalyzed by Pt-Graphene Sensitized with Br-dye under Visible Light Irradiation
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摘要 ~3He是理想的核聚变燃料,但是地球上~3He的储量十分有限,大约只有500 kg.我们报道了在可见光光照条件下,溴染料敏化担载Pt石墨烯催化水还原为氢气过程中伴生少量氘和氦的实验现象.结果表明在温和条件下自水中的质子生产氘和氦的是可能的. 3 He is a perfect fuel for nuclear fusion, however, the amount of 3 He on the earth is very limited, only around 500 kg. Here, we report that small amount of deuterium and helium can be produced during photocatalytie hydrogen evolution from water catalyzed by Pt-graphene sensitized with Br-dye under visible light irradiation. This work raises a mild route to generate deuterium ( D2 ) and helium (He) from proton in the water under very mild conditions.
作者 吕功煊 田彬
出处 《分子催化》 EI CAS CSCD 北大核心 2017年第2期101-104,共4页 Journal of Molecular Catalysis(China)
基金 The National Natural Science Foundation of China(Grant No.21433007 and 21673262) the 973 Program of Department of Sciences and Technology China(Grant No.2013CB632404)
关键词 光催化还原质子 生成氘和氦 可见光辐照 photocatalytic reduction of proton formation of deuterium and helium visible light irradiation
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