摘要
利用水热合成技术,选择低毒NaAsO_2为起始原料,通过调节反应物浓度、控制反应温度、反应时间等方法合成了一种以{MAs_6Mo_6}为基本框架的砷钼酸盐,通过元素分析、IR、TG、和X-射线衍射对晶体结构进行了表征,对该化合物的性质进行了初步研究.
Using the hydrothermal synthesis technology, low toxicity to choose NaAsO2 as the starting material, by adjusting the concentration of reactants, control of reaction temperature and time, an arsenmolybdate used { MAs6Mo6} t as a basic framework is synthetized. The arsenmolybdate are characterizedby elemental analysis, IR, TG, and X - ray diffraction on the crystal structure and the properties of the the compounds are studied.
作者
夏林
苏占华
赵志凤
周百斌
马秀娟
丛博文
Xia Lin Su Zhanhua Zhao Zhifeng Zhou Baibin Ma Xiujuan Cong Bowen(Key Laboratory of Synthesis of Functional Materials and Green Catalysis, Colleges of Heilongjiang Province, Harbin Normal Universit)
出处
《哈尔滨师范大学自然科学学报》
CAS
2016年第5期60-64,共5页
Natural Science Journal of Harbin Normal University
关键词
砷钼酸盐
水热合成
晶体结构
Arsenomolybdate
Hydro - thermal synthesis
