简单易得试剂与磷-氢化合物交叉偶联合成有机磷化合物

Recent Advances in the Synthesis of Organophosphorus Compounds via Cross Coupling between Readily Available Materials and P—H Compounds

综述了近年来利用磷-氢化合物与简单易得试剂交叉偶联合成有机磷化合物的研究进展.主要包括利用末端炔烃与磷-氢化合物通过C—H/P—H交叉偶联合成炔基膦化合物,利用简单易得的含氧、含硫或含氮有机化合物与磷-氢化合物交叉偶联构建sp^2/sp^3-C—P键或P—Z键,并对部分反应的机理进行扼要总结.

This mini-review focuses on the recent advances in the synthesis of organophosphorus compounds via cross cou- pling of P--H compounds with readily available starting materials, mainly including the reactions of terminal alkynes and heteroatom compounds （oxygen, sulfur or nitrogen-contained compounds） with P--H compounds forming sp-C--P, spE-C--P, sp3-C--P, and P--Z bonds. Related reaction mechanisms are also discussed.