摘要
以1,10-邻菲咯啉为原料,合成了标题化合物的配体(L),再以相同的原料,生成1,10-邻菲咯啉-5,6-二酮(D),D与KMnO4在碱性条件下,水-醇溶液中加热回流,得到标题配合物(B)。L及其配合物被元素分析、1H NMR和X-射线单晶衍射表征,结果表明:L属于正交晶系,Pbcn空间群,a=1.1091(3)nm,b=0.66174(15)nm,c=1.9168(4)nm.α=β=γ=90.00゜.B属于正交晶系,P21212空间群,a=1.37672(15)nm,b=0.63621(7)nm,c=0.83365(9)nm.α=β=γ=90.00゜,M n(Ⅵ)与4个H2O分子和两个配体羧酸的氧原子形成变形8面体。L-B:C C D C
The title compound (L) and it's Mn(Ⅵ) complexe(B) have been synthesized, they are all with the phenanthrene material. They have been characterized by elemental analysis, 1H NMR and X- ray crystal diffraction. Results show L and B the orthogonal system,L is Pbcn space group, a=1.1091(3)nm, b=0.66174(15)nm, c=1.9168(4)nm,α=β=γ= 90.00°. B is P21212 space group, a=1.37672(15)nm, b=0. 63621(7)nm, c=0.83365(9) nm.,α=β=γ=90.00° . Mn(Ⅵ) with the oxygen atoms of four water molecules and the oxygen atom of two carboxylic acid mole-ules is forming a tetragonally distorted octahedral structure. CCDC, L-B: 1420013-1420014.
作者
李源祥
易君明
陈明华
LI Yuan Xiang YU Jun Ming CHEN Ming Hua(Xingyi NO. 8 middle school, Xingyi, Guizhou 562400 Xingyi Normal University for Nationalities, Xingyi,Guizhou 562400)
出处
《兴义民族师范学院学报》
2017年第1期121-124,共4页
Journal of Minzu Normal University of Xingyi
基金
贵州省科技厅联合基金(黔科合LH字[2014]7411号)资助项目