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DMAP-Catalyzed [4+2] Cycloaddition of α,β-Unsaturated Carboxylic Acids with Ketones for Synthesis of ,β-Unsaturated δ-Lactones (pages 397–400) 被引量:1

DMAP-Catalyzed [4+2] Cycloaddition of α,β-Unsaturated Carboxylic Acids with Ketones for Synthesis of ,β-Unsaturated δ-Lactones (pages 397–400)
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摘要 The DMAP-catalyzed [4+2] cycloaddition of α,β-unsaturated carboxylic acids with ketones furnishing α,β-unsaturated δ-lactones in good yields (up to 80%) is described, which is the first example of remote -C(sp^3)-H activation of α,β-unsaturated carboxylic acids facilitated by DMAP, a pyridine-based catalyst. The DMAP-catalyzed [4+2] cycloaddition of α,β-unsaturated carboxylic acids with ketones furnishing α,β-unsaturated δ-lactones in good yields (up to 80%) is described, which is the first example of remote -C(sp^3)-H activation of α,β-unsaturated carboxylic acids facilitated by DMAP, a pyridine-based catalyst.
出处 《Chinese Journal of Chemistry》 SCIE CAS CSCD 2017年第4期397-400,共4页 中国化学(英文版)
基金 This work is supported by the National Natural Science Foundation of China (No. 21372074).
关键词 DMAP CYCLOADDITION α β-unsaturated carboxylic acids α β-unsaturated δ-lactones DMAP, cycloaddition, α,β-unsaturated carboxylic acids, α,β-unsaturated δ-lactones
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