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Selective oxidation of alcohols with H2O2 catalyzed by zinc polyoxometalate immobilized on multi-wall carbon nanotubes modified with ionic liquid 被引量:3

Selective oxidation of alcohols with H_2O_2 catalyzed by zinc polyoxometalate immobilized on multi-wall carbon nanotubes modified with ionic liquid
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摘要 In this work,acid functionalized multi-wall carbon nanotubes(MWCNTs) were modified with imidazolium-based ionic liquids.The selective oxidation of various alcohols with hydrogen peroxide catalyzed by [PZnMo2W9O39]^5-,ZnPOM,supported on ionic liquids-modified with MWCNTs,MWCNTAPIB,is reported.This catalyst[ZnPOM@APIB-MWCNT],was characterized by X-ray diffraction,scanning electron microscopy(SEM) and FT-IR spectroscopic methods.This heterogeneous catalyst exhibited high stability and reusability in the oxidation reaction without loss of its catalytic performance. In this work,acid functionalized multi-wall carbon nanotubes(MWCNTs) were modified with imidazolium-based ionic liquids.The selective oxidation of various alcohols with hydrogen peroxide catalyzed by [PZnMo2W9O39]^5-,ZnPOM,supported on ionic liquids-modified with MWCNTs,MWCNTAPIB,is reported.This catalyst[ZnPOM@APIB-MWCNT],was characterized by X-ray diffraction,scanning electron microscopy(SEM) and FT-IR spectroscopic methods.This heterogeneous catalyst exhibited high stability and reusability in the oxidation reaction without loss of its catalytic performance.
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 2017年第5期971-975,共5页 中国化学快报(英文版)
基金 the Yazd University Research Council for partial support of this work
关键词 Immobilized ionic liquid [PZnMo2W9O39]^5- Hydrogen peroxide Oxidation Alcohol Heterogeneous catalyst Immobilized ionic liquid [PZnMo2W9O39]^5- Hydrogen peroxide Oxidation Alcohol Heterogeneous catalyst
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