摘要
A novel hybrid type photosensitive resin for stereolithography in 3D printing was prepared with bisphenol A type epoxy diacrylate （EA-612）, tripropylene glycol diacrylate （TPGDA）,ethoxylated trimethyolpropane triacrylate（EO3TMPTA）, cycloaliphatic diepoxide（ERL-4221）,polycaprolactonepolyol（Polyol-0301）,1-hydroxy-cyclohphenyl ketone（Irgacure184）, and a mixture of triarylsulfonium hexafluoroantimonate salts （Ar3SSbF6）. The novel hybrid type photosensitive resin was the photosensitive resin of an epoxy-acrylate hybrid system, which proceeded free radical polymerization and cationic polymerization in ultraviolet （UV） laser. Cuboid parts and double-cantilever parts were fabricated by using a stereolithography apparatus with the novel hybrid type photosensitive resin as the processing material,and the dimension shrinkage factor and the curl factor were tested. The shrinkage factor was less than 2.00%,and the curl factor was less than 8.00%, which showed that the accuracy of the fabricated parts was high with the photosensitive resin for stereolithography in 3D printing.
A novel hybrid type photosensitive resin for stereolithography in 3D printing was prepared with bisphenol A type epoxy diacrylate （EA-612）, tripropylene glycol diacrylate （TPGDA）,ethoxylated trimethyolpropane triacrylate（EO3TMPTA）, cycloaliphatic diepoxide（ERL-4221）,polycaprolactonepolyol（Polyol-0301）,1-hydroxy-cyclohphenyl ketone（Irgacure184）, and a mixture of triarylsulfonium hexafluoroantimonate salts （Ar3SSbF6）. The novel hybrid type photosensitive resin was the photosensitive resin of an epoxy-acrylate hybrid system, which proceeded free radical polymerization and cationic polymerization in ultraviolet （UV） laser. Cuboid parts and double-cantilever parts were fabricated by using a stereolithography apparatus with the novel hybrid type photosensitive resin as the processing material,and the dimension shrinkage factor and the curl factor were tested. The shrinkage factor was less than 2.00%,and the curl factor was less than 8.00%, which showed that the accuracy of the fabricated parts was high with the photosensitive resin for stereolithography in 3D printing.
基金
Funded by the National Natural Science Foundation of China(No.51563017)
the Natural Science Foundation of Jiangxi Province(No.20142BAB206029)
